Product ID:1,3-BENZENEDIAMINE, O-352
MSDS Date:09/01/1988
FSC:6810
NIIN:00N066119
MSDS Number: CBDFT

Emergency Phone: 215-692-3026

Info Phone: 215-692-3026

Cage: 84898

Telephone: 610-692-3026

Cage: 8Y898

M-PHENYLENEDIAMINE; (1.3-BENZENEDIAMINE)

CAS: 108-45-2

RTECS: SS7700000

OSHA PEL N/K

ACGIH TLV: 0.1 MG/M3

LD50 LC50 Mixture:LD50(ORAL,RAT):650 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONTACT LENSES SHOULD NOT BE WORN IN
LABORATORY. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS-AVOID
DIRECT PHYSICAL CONTACT! MAY BE RAPIDLY ABSORBED THROUGH THE SKIN
WITH POTENTIAL ADVERSE HEALTH EFFE CTS. CAN BE HARMFUL IF
SWALLOWED, INHALED AND ABSORBED THROUGH THE SKIN. CAN CAUSE EYE
IRRITATION. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:DUST AND/OR VAPORS CAN CAUSE
IRRITATION TO RESPIRATORY TRACT. CAN BE IRRITATING TO MUCOUS
MEMBRANES. CAN CAUSE AN ALLERGIC SKIN REACTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:AN ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POIS.
IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE
OBTAINED FROM POIS CTL CTR. SKIN:IF NO BURNS HAVE OCCURRED, USE
SOAP & W ATER TO CLEANSE SKIN. REMOVE & WASH CONTAM CLTHG. GET MED
ATTN IF NEC. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYG IF
PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT HAS STOPPED BRTHG ADMIN
ARTF(SUPDAT)

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. SWEEP UP AND PLACE IN AN APPROPRIATE
CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE
ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. STORE
ONLY WITH COMPATIBLE CHEMICALS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HNDL CHEM/ITS CNTNR. PROD IS FURNISHED FOR LAB USE ONLY! MFR'S
PRODS MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL
PRODS, FOOD ADD ITIVES/AS HOUSEHOLD CHEMS.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . USE APPROPRIATE OSHA/MSMA APPROVED SAFETY
EQUIPMENT.
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:RESP. IF PATIENT IS IN CARDIAC ARREST ADMINISTER CPR.
CONTINUE LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIVED.
GET MEDICAL ATTENTION IF NECESSARY. INGEST:CALL MD IMMED .
EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF 15 MIN, SEEK ASSISTANCE
FROM MD .

Boiling Pt:B.P. Text:>540F,>282C
Melt/Freeze Pt:M.P/F.P Text:>147F,>64C
Spec Gravity:1.139
Solubility in Water:SOLUBLE
Appearance and Odor:STENCH! WHITE CRYSTALLINE SOLID.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG ACIDS, OXIDIZING AGENTS AND CHLOROFORMATES.
Stability Condition to Avoid:HNDL & STORE UNDER NITROGEN. SENSITIVE TO
LIGHT-DARK COLOR DOES NOT AFFECT PURITY. REACTS W/ACID HALIDES &
ANHYDRIDES.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.